
The results were published in the 17 July edition of the influential scientific journal Advanced Materials.
Functional coatings, for example with highly water-resistant or
antibacterial properties, have at their surface nano-sized molecular
groups that provide these specific properties. But up to now, these
molecular groups are easily and irreversibly damaged by minor contact
with their surface (such as by scratching), quickly causing their
properties to be lost. This has been a big limitation to the possible
applications of these coatings. Researcher Catarina Esteves of the
department of Chemical Engineering and Chemistry at TU/e and her
colleagues have now found a solution to this problem. They have done
this by developing surfaces with special 'stalks' carrying the
functional chemical groups at their ends, and mixing these through the
coating. If the outer surface layer is removed by scratching, the
'stalks' in the underlying layer re-orient to the new surface, thereby
restoring the function.
This development can be of great importance for many applications.
For example it will be possible to make a self-cleaning car, with a
highly water-resistant coating that keeps this self-cleaning property
for long periods. The superficial scratches will be self-repaired and
the water droplets simply roll off the car, taking dirt with them. An
occasional rain shower is all that's needed to keep the car clean. In
the same way, products like mobile phones, solar panels or even aircraft
will remain clean for a longer time. For aircraft a cleaner surface
means less air resistance, which in turn reduces fuel consumption. Other
applications are contact lenses that self-repair their scratches, and
coatings that resist the formation of algae, which is an advantage for
ships. A limitation of the new technology is that it only works with
superficial scratches that do not completely penetrate the coating.
Researcher Esteves and her team now intend to further develop this
finding together with other universities and with industrial partners.
She expects the first coatings to be ready for production within six to
eight years, at prices comparable to those of today's coatings.
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